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Two‐Step Adsorption/Desorption on a Jungle‐Gym‐Type Porous Coordination Polymer
Author(s) -
Uemura Kazuhiro,
Yamasaki Yukari,
Komagawa Yuki,
Tanaka Kazuhiro,
Kita Hidetoshi
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702390
Subject(s) - adsorption , octane , desorption , chemistry , porosity , polymer , chemical engineering , crystallography , organic chemistry , engineering
Flexible frameworks : Unique two‐step isotherms were observed for the adsorption/desorption of propan‐2‐ol on [{Zn 2 (1,4‐benzenedicarboxylate) 2 (1,4‐diazabicyclo[2.2.2]octane)} n ] with hydrophobic open spaces. The isotherms were characterized by means of thermal analysis and single‐crystal X‐ray diffraction (see picture).