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Surface Noncovalent Bonding for Rational Design of Hierarchical Molecular Self‐Assemblies
Author(s) -
Bléger David,
Kreher David,
Mathevet Fabrice,
Attias AndréJean,
Schull Guillaume,
Huard Axel,
Douillard Ludovic,
FioriniDebuischert Céline,
Charra Fabrice
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702376
Subject(s) - parallels , non covalent interactions , block (permutation group theory) , polymer , surface (topology) , polymer science , chemistry , surface protein , computer science , nanotechnology , materials science , molecule , organic chemistry , engineering , mathematics , combinatorics , hydrogen bond , mechanical engineering , geometry , virology , biology
Clip chemistry : When a fully deterministic strategy that parallels polymer chemistry is used, mono‐, bi‐, and trifunctional clip‐bearing building blocks form noncovalent surface‐self‐assembled dimers, polymers, and 2D networks, respectively (see scheme). These entities can then be subjected to further higher‐level manipulations, as shown by controlled reorganization (cyclization) of a polymerlike chain around a molecular block.