Self‐Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low‐Valent Uranium | Zendy

Nocton Grégory | Zendy; Burdet Fabien | Zendy; Pécaut Jacques | Zendy; Mazzanti Marinella | Zendy

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Self‐Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low‐Valent Uranium

Author(s) -

Nocton Grégory,

Burdet Fabien,

Pécaut Jacques,

Mazzanti Marinella

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702374

Subject(s) - uranium , valence (chemistry) , stoichiometry , hydrolysis , zeolite , crystallography , chemistry , topology (electrical circuits) , inorganic chemistry , materials science , catalysis , organic chemistry , metallurgy , mathematics , combinatorics

Cores for celebration! Hydrolysis of trivalent uranium compounds with a stoichiometric amount of water leads to mixed‐valence (U IV /U V ) discrete clusters with the U 6 O 8 core and with the unprecedented U 12 O 20 core (see picture, right; U green, O red), and to the assembly of U 6 O 8 clusters into extended 3D networks of zeolite‐like topology with nanosized cavities (left; U pink, K violet, O red, F green).

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