Highly Isospecific Styrene Polymerization Catalyzed by Single‐Component Bridged Bis(indenyl) Allyl Yttrium and Neodymium Complexes | Zendy

Rodrigues AnneSophie | Zendy; Kirillov Evgueni | Zendy; Roisnel Thierry | Zendy; Razavi Abbas | Zendy; Vuillemin Bruno | Zendy; Carpentier JeanFrançois | Zendy

Premium

Highly Isospecific Styrene Polymerization Catalyzed by Single‐Component Bridged Bis(indenyl) Allyl Yttrium and Neodymium Complexes

Author(s) -

Rodrigues AnneSophie,

Kirillov Evgueni,

Roisnel Thierry,

Razavi Abbas,

Vuillemin Bruno,

Carpentier JeanFrançois

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702353

Subject(s) - styrene , yttrium , neodymium , polystyrene , polymerization , tacticity , polymer chemistry , catalysis , copolymer , chemistry , ligand (biochemistry) , materials science , polymer , organic chemistry , laser , biochemistry , physics , receptor , optics , oxide

Me, myself, and styrene : Yttrium and neodymium allyl complexes bearing a bridged bis(indenyl) ligand (Cat.; Ln=Y, Nd) are active single‐component catalysts for the polymerization of styrene up to 120 °C, giving highly isotactic polystyrene (iPS), with number‐average molecular weights ( M n ) of 12 000–102 000 and polydispersities ( M w / M n ) of 1.5–2.6.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research