Formation of Mixed‐Valent Aryltellurenyl Halides RX 2 TeTeR | Zendy

Beckmann Jens | Zendy; Hesse Malte | Zendy; Poleschner Helmut | Zendy; Seppelt Konrad | Zendy

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Formation of Mixed‐Valent Aryltellurenyl Halides RX 2 TeTeR

Author(s) -

Beckmann Jens,

Hesse Malte,

Poleschner Helmut,

Seppelt Konrad

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702341

Subject(s) - halide , monomer , chemistry , ab initio , ab initio quantum chemistry methods , crystallography , charge (physics) , computational chemistry , inorganic chemistry , physics , organic chemistry , molecule , polymer , quantum mechanics

Mixed doubles : The mixed‐valent dinuclear aryltellurenyl halides PhBr 2 TeTePh (see picture), and RX 2 TeTeR (X=ClBr, R=2,6‐Mes 2 C 6 H 3 ), the monomeric 2,6‐Mes 2 C 6 H 3 TeI, and the charge‐transfer complex 2,6‐Mes 2 C 6 H 3 TeI⋅⋅⋅I 2 are presented. The stability of H 3 CEX (E=S, Se, Te; X=F, Cl, Br, I) as determined by ab initio methods are also discussed.

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