Premium
Formation of Mixed‐Valent Aryltellurenyl Halides RX 2 TeTeR
Author(s) -
Beckmann Jens,
Hesse Malte,
Poleschner Helmut,
Seppelt Konrad
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702341
Subject(s) - halide , monomer , chemistry , ab initio , ab initio quantum chemistry methods , crystallography , charge (physics) , computational chemistry , inorganic chemistry , physics , organic chemistry , molecule , polymer , quantum mechanics
Mixed doubles : The mixed‐valent dinuclear aryltellurenyl halides PhBr 2 TeTePh (see picture), and RX 2 TeTeR (X=ClBr, R=2,6‐Mes 2 C 6 H 3 ), the monomeric 2,6‐Mes 2 C 6 H 3 TeI, and the charge‐transfer complex 2,6‐Mes 2 C 6 H 3 TeI⋅⋅⋅I 2 are presented. The stability of H 3 CEX (E=S, Se, Te; X=F, Cl, Br, I) as determined by ab initio methods are also discussed.