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Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in Diameter
Author(s) -
Park Young Kwan,
Choi Sang Beom,
Kim Hyunuk,
Kim Kimoon,
Won ByoungHo,
Choi Kihang,
Choi JungSik,
Ahn WhaSeung,
Won Nayoun,
Kim Sungjee,
Jung Dong Hyun,
Choi SeungHoon,
Kim GhyungHwa,
Cha SunShin,
Jhon Young Ho,
Yang Jin Kuk,
Kim Jaheon
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702324
Subject(s) - mesoporous material , sorption , carboxylate , metal organic framework , luminescence , molecule , ferrocene , metal , ion , crystal structure , materials science , chemistry , inorganic chemistry , nanotechnology , crystallography , organic chemistry , adsorption , optoelectronics , catalysis , electrochemistry , electrode
Supersized pores : A new mesoporous metal–organic framework that is mainly composed of Tb 3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas‐sorption measurements and luminescence studies.