Bimetallic Ru–Sn Nanoparticle Catalysts for the Solvent‐Free Selective Hydrogenation of 1,5,9‐Cyclododecatriene to Cyclododecene | Zendy

Adams Richard D. | Zendy; Boswell Erin M. | Zendy; Captain Burjor | Zendy; Hungria Ana B. | Zendy; Midgley Paul A. | Zendy; Raja Robert | Zendy; Thomas John Meurig | Zendy

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Bimetallic Ru–Sn Nanoparticle Catalysts for the Solvent‐Free Selective Hydrogenation of 1,5,9‐Cyclododecatriene to Cyclododecene

Author(s) -

Adams Richard D.,

Boswell Erin M.,

Captain Burjor,

Hungria Ana B.,

Midgley Paul A.,

Raja Robert,

Thomas John Meurig

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702274

Subject(s) - bimetallic strip , catalysis , tin , nanoparticle , solvent , chemistry , cluster (spacecraft) , nuclear chemistry , organic chemistry , materials science , nanotechnology , computer science , programming language

Tin(n)y catalysts : Bimetallic RuSn supported nanoparticle catalysts (see picture; Ru green, Sn blue, O red), prepared from the carbonyl‐cluster precursors [Ru 4 (μ 4 ‐SnPh) 2 (μ‐SnPh 2 ) 4− x (CO) 12− x ] ( x =0, 2, 3, 4) are shown to be active catalysts for the highly selective hydrogenation of 1,5,9‐cyclododecatriene to cyclododecene under mild conditions.

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