Synthesis and Reactivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes | Zendy

Anderson Donde R. | Zendy; Lavallo Vincent | Zendy; O'Leary Daniel J. | Zendy; Bertrand Guy | Zendy; Grubbs Robert H. | Zendy

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Synthesis and Reactivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes

Author(s) -

Anderson Donde R.,

Lavallo Vincent,

O'Leary Daniel J.,

Bertrand Guy,

Grubbs Robert H.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702085

Subject(s) - catalysis , olefin metathesis , alkyl , steric effects , reactivity (psychology) , chemistry , metathesis , aryl , olefin fiber , organic chemistry , combinatorial chemistry , medicinal chemistry , polymerization , medicine , alternative medicine , pathology , polymer

All it's CAACed up to be! Cyclic (alkyl)(amino)carbenes (CAACs) can be used as ligands for olefin metathesis catalysis. A dramatic steric effect of the N‐aryl group of the CAAC on catalyst activity was observed and utilized to develop a new catalyst with activity comparable to standard commercially available catalysts.

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