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Strong Evidence for a Transient Phosphinidenoid Complex
Author(s) -
Özbolat Aysel,
von Frantzius Gerd,
Pérez Janaina Marinas,
Nieger Martin,
Streubel Rainer
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701962
Subject(s) - butyraldehyde , iodide , chemistry , transient (computer programming) , methyl iodide , photochemistry , inorganic chemistry , organic chemistry , catalysis , computer science , operating system
Caught in the trap : Two different routes to the thermally unstable phosphinidenoid complex I are described, and chemical evidence for this novel intermediate is provided through selective reactions. For example, methyl iodide, dimethylcyanamide, or butyraldehyde furnished complexes II, III , and IV (see scheme) under very mild conditions.