Trifluoromethyl Coordination and CF Bond Activation at Calcium | Zendy

Barrett Anthony G. M. | Zendy; Crimmin Mark R. | Zendy; Hill Michael S. | Zendy; Hitchcock Peter B. | Zendy; Procopiou Panayiotis A. | Zendy

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Trifluoromethyl Coordination and CF Bond Activation at Calcium

Author(s) -

Barrett Anthony G. M.,

Crimmin Mark R.,

Hill Michael S.,

Hitchcock Peter B.,

Procopiou Panayiotis A.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701945

Subject(s) - fluorine , trifluoromethyl , calcium , fluoride , chemistry , cleavage (geology) , bond cleavage , atom (system on chip) , coordination number , crystallography , stereochemistry , computer science , inorganic chemistry , ion , materials science , organic chemistry , catalysis , operating system , fracture (geology) , composite material , alkyl

Fluoral arrangement : The calcium β‐diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF 3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes CF bond cleavage through the formation of a heteroleptic calcium fluoride complex.

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