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Trifluoromethyl Coordination and CF Bond Activation at Calcium
Author(s) -
Barrett Anthony G. M.,
Crimmin Mark R.,
Hill Michael S.,
Hitchcock Peter B.,
Procopiou Panayiotis A.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701945
Subject(s) - fluorine , trifluoromethyl , calcium , fluoride , chemistry , cleavage (geology) , bond cleavage , atom (system on chip) , coordination number , crystallography , stereochemistry , computer science , inorganic chemistry , ion , materials science , organic chemistry , catalysis , operating system , fracture (geology) , composite material , alkyl
Fluoral arrangement : The calcium β‐diketiminate complex 1 (see scheme) not only exhibits an unexpected and unprecedented binding mode of a CF 3 group, from which one fluorine atom coordinates to the Ca center, but also undergoes CF bond cleavage through the formation of a heteroleptic calcium fluoride complex.