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Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis
Author(s) -
Ackermann Lutz,
Born Robert,
ÁlvarezBercedo Paula
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701727
Subject(s) - ruthenium , aryl , carbene , catalysis , hydrosilylation , chemistry , combinatorial chemistry , scheme (mathematics) , sequence (biology) , organic chemistry , computer science , mathematics , biochemistry , mathematical analysis , alkyl
Jack of all trades? A ruthenium(IV) carbene complex catalyzes the diastereoselective direct arylation of alkenes using aryl chlorides with high efficiency, which sets the stage for the development of a direct arylation–hydrosilylation sequence (see scheme).