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Discrete Triangular Tripalladium Sandwich Complexes of Arenes
Author(s) -
Murahashi Tetsuro,
Fujimoto Mayu,
Kawabata Yurika,
Inoue Ryou,
Ogoshi Sensuke,
Kurosawa Hideo
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701665
Subject(s) - derivative (finance) , ligand (biochemistry) , nuclear magnetic resonance spectroscopy , chemistry , metal , spectroscopy , atom (system on chip) , stereochemistry , crystallography , polymer chemistry , organic chemistry , receptor , physics , engineering , business , biochemistry , quantum mechanics , finance , embedded system
Sandwich triangles : A bis([2.2]paracyclophane)tripalladium complex ( 1 ) was isolated and characterized by NMR spectroscopy, and a mixed‐ligand derivative was structurally characterized. These complexes are the first isolated μ 3 ‐arene trimetal complexes of a Group 10 metal. Complex 1 undergoes facile release of a Pd 0 atom (see scheme) and as such may be regarded as a Pd 0 reservoir.