The Tungstogermanate [Ce 20 Ge 10 W 100 O 376 (OH) 4 (H 2 O) 30 ] 56− : A Polyoxometalate Containing 20 Cerium(III) Atoms | Zendy

Bassil Bassem S. | Zendy; Dickman Michael H. | Zendy; Römer Isabella | Zendy; von der Kammer Bernd | Zendy; Kortz Ulrich | Zendy

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The Tungstogermanate [Ce 20 Ge 10 W 100 O 376 (OH) 4 (H 2 O) 30 ] 56− : A Polyoxometalate Containing 20 Cerium(III) Atoms

Author(s) -

Bassil Bassem S.,

Dickman Michael H.,

Römer Isabella,

von der Kammer Bernd,

Kortz Ulrich

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701422

Subject(s) - cerium , polyoxometalate , lanthanide , dimer , aqueous solution , atom (system on chip) , aqueous medium , ion , chemistry , crystallography , inorganic chemistry , catalysis , organic chemistry , computer science , embedded system

Big W : One of the largest polytungstates, the 20 cerium(III) atom tungstogermanate [Ce 20 Ge 10 W 100 O 376 (OH) 4 (H 2 O) 30 ] 56− ( 1 ), has been synthesized from Ce III ions and [α‐GeW 9 O 34 ] 10− in aqueous acidic medium at pH 5.0. Polyanion 1 represents the first lanthanide‐substituted tungstogermanate and can be described as a dimer that is linked through long CeO(W) bridges.

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