Regio‐ and Stereoselective Synthesis of Enamides and Dienamides by Ruthenium‐Catalyzed Co‐Oligomerization of  N ‐Vinylamides with Alkenes or Alkynes | Zendy

Tsujita Hiroshi | Zendy; Ura Yasuyuki | Zendy; Matsuki Shingo | Zendy; Wada Kenji | Zendy; Mitsudo Takeaki | Zendy; Kondo Teruyuki | Zendy

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Regio‐ and Stereoselective Synthesis of Enamides and Dienamides by Ruthenium‐Catalyzed Co‐Oligomerization of N ‐Vinylamides with Alkenes or Alkynes

Author(s) -

Tsujita Hiroshi,

Ura Yasuyuki,

Matsuki Shingo,

Wada Kenji,

Mitsudo Takeaki,

Kondo Teruyuki

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701356

Subject(s) - ruthenium , catalysis , ethylene , chemistry , stereoselectivity , acrylate , methyl acrylate , combinatorial chemistry , medicinal chemistry , organic chemistry , copolymer , polymer

The zero‐valent ruthenium complex (η 6 ‐1,3,5‐cyclooctatriene)bis(η 2 ‐dimethyl fumarate)ruthenium effectively catalyzes the highly selective codimerization of N ‐vinylamides with alkenes or alkynes and was successfully applied in the cotrimerization of N ‐vinylamides with ethyl acrylate and ethylene (see scheme). These reactions offer a rapid and atom‐economical synthesis of biologically and synthetically important enamides and dienamides.

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