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Bis(1,2,3,4‐η 4 ‐anthracene)ferrate(1−): A Paramagnetic Homoleptic Polyarene Transition‐Metal Anion
Author(s) -
Brennessel William W.,
Jilek Robert E.,
Ellis John E.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701353
Subject(s) - homoleptic , chemistry , paramagnetism , transition metal , metal , anthracene , yield (engineering) , inorganic chemistry , crystallography , photochemistry , organic chemistry , materials science , catalysis , physics , condensed matter physics , metallurgy
Magnetic personalities : [Fe(η 4 ‐C 14 H 10 ) 2 ] − is an unprecedented example of an anionic 17‐electron homoleptic polyarene transition‐metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides “naked” atomic Fe −I in its reaction with 1,3‐butadiene to yield the first structurally authenticated homoleptic bis(1,3‐butadiene) metal complex, [Fe(η 4 ‐C 4 H 6 ) 2 ] − (see structure).
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