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An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo) 2 (μ,η 3 ‐P 3 )(μ,η 2 ‐PS)]
Author(s) -
Gregoriades Laurence J.,
Balázs Gábor,
Brunner Eike,
Gröger Christian,
Wachter Joachim,
Zabel Manfred,
Scheer Manfred
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701343
Subject(s) - crystallography , group (periodic table) , supramolecular chemistry , ligand (biochemistry) , chemistry , metal , polymer , nuclear magnetic resonance spectroscopy , block (permutation group theory) , spectroscopy , derivative (finance) , stereochemistry , crystal structure , physics , organic chemistry , combinatorics , biochemistry , receptor , mathematics , quantum mechanics , financial economics , economics
Unusual suspect: The complex [(Cp*Mo) 2 (μ,η 3 ‐P 3 )(μ,η 2 ‐PS)] reacts with CuI and Ag[Al{OC(CF 3 ) 3 } 4 ] to form two novel linear polymers (see structure of CuI derivative; Cu light blue, I violet, Mo blue, P pink, S yellow). Even with X‐ray crystallographic data available, the fact that the sulfur atoms in these polymers do not coordinate to the Group 11 metal centers could only be established with the help of 31 P MAS NMR spectroscopy. Cp*=C 5 Me 5