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A Coordination Polymer of Gold(I) with Heterotactic Architecture and a Comparison of the Structures of Isotactic, Syndiotactic, and Heterotactic Isomers
Author(s) -
Wheaton Craig A.,
Puddephatt Richard J.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701325
Subject(s) - tacticity , coordination polymer , polymer , materials science , polymer chemistry , chemistry , organic chemistry , polymerization
A tactic‐al approach : By use of gold chemistry the first organic–inorganic polymer with a heterotactic architecture has been synthesized, and has enabled the first direct structural comparison of coordination polymers with isotactic, syndiotactic, and heterotactic architectures (see picture: naphthyl groups green, 4,4′‐bipyridine ligands blue, phenyl gray, Au red, P purple).