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Efficient CuO‐Nanoparticle‐Catalyzed CS Cross‐Coupling of Thiols with Iodobenzene
Author(s) -
Rout Laxmidhar,
Sen Tamal K.,
Punniyamurthy Tharmalingam
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701282
Subject(s) - iodobenzene , aryl , halide , catalysis , nanoparticle , alkyl , chemistry , combinatorial chemistry , coupling (piping) , coupling reaction , organic chemistry , nanotechnology , materials science , metallurgy
Cheap but good : Readily available CuO nanoparticles are not only less expensive than other catalysts used for the CS cross‐coupling of thiols with aryl halides, but they are also effective at a moderate temperature and low concentration. The title reaction proceeds with a variety of alkyl and aryl thiols to give the corresponding sulfides in high yields (see scheme).