Asymmetric Organocatalytic α‐Arylation of Aldehydes | Zendy

Alemán José | Zendy; Cabrera Silvia | Zendy; Maerten Eddy | Zendy; Overgaard Jacob | Zendy; Jørgensen Karl Anker | Zendy

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Asymmetric Organocatalytic α‐Arylation of Aldehydes

Author(s) -

Alemán José,

Cabrera Silvia,

Maerten Eddy,

Overgaard Jacob,

Jørgensen Karl Anker

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701207

Subject(s) - enantioselective synthesis , chemistry , trimethylsilyl , status quo , solvent , optically active , scheme (mathematics) , organic chemistry , catalysis , combinatorial chemistry , mathematics , political science , law , mathematical analysis

Quinone pro quo : The organocatalytic enantioselective α‐arylation of aldehydes using quinones as the aromatic partner was carried out. The reaction proceeds well using H 2 O or EtOH/H 2 O mixtures as solvent. The corresponding optically active α‐arylated aldehydes are obtained in high yields and with excellent enantioselectivities (see scheme; TMS: trimethylsilyl).

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