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The Geometric and Electronic Structure of a One‐Electron‐Oxidized Nickel(II) Bis(salicylidene)diamine Complex
Author(s) -
Storr Tim,
Wasinger Erik C.,
Pratt Russell C.,
Stack T. Daniel P.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701194
Subject(s) - delocalized electron , diamine , valence (chemistry) , class (philosophy) , ligand (biochemistry) , chemistry , nickel , electron delocalization , electron , crystallography , stereochemistry , computer science , polymer chemistry , physics , organic chemistry , quantum mechanics , biochemistry , receptor , artificial intelligence
Class III delocalization? The isolation and analysis of the ligand‐radical title complex has allowed description of the changes in bonding from the reduced form as well as the extent of delocalization. The intense low‐energy absorption of the oxidized complex can be described as a ligand‐radical transition of a highly delocalized class III mixed‐valence compound.