Stepwise Intermetal Borylene Transfer: Synthesis and Structure of Mono‐ and Dinuclear Cobalt–Borylene Complexes | Zendy

Braunschweig Holger | Zendy; Forster Melanie | Zendy; Radacki Krzysztof | Zendy; Seeler Fabian | Zendy; Whittell George R. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Stepwise Intermetal Borylene Transfer: Synthesis and Structure of Mono‐ and Dinuclear Cobalt–Borylene Complexes

Author(s) -

Braunschweig Holger,

Forster Melanie,

Radacki Krzysztof,

Seeler Fabian,

Whittell George R.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701142

Subject(s) - chemistry , cobalt , transmetalation , ligand (biochemistry) , stereochemistry , organic chemistry , receptor , catalysis , biochemistry

Step by step : Stepwise transmetalation of the borylene ligand BN(SiMe 3 ) 2 from [(OC) 5 WBN(SiMe 3 ) 2 ] to [(η 5 ‐C 5 H 5 )Co(CO) 2 ] gives access to the first mono‐ and dinuclear cobalt borylene species and provides convincing evidence that the intermetal borylene transfer proceeds by an associative process with a heterodimetallic intermediate (see structure) without generation of an intermediate free borylene species.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research