Synthesis of Molecular Vanadium(III) Phosphonates | Zendy

Khanra Sumit | Zendy; Kloth Marc | Zendy; Mansaray Hassanatu | Zendy; Muryn Christopher A. | Zendy; Tuna Floriana | Zendy; Sañudo E. Carolina | Zendy; Helliwell Madeleine | Zendy; McInnes Eric J. L. | Zendy; Winpenny Richard E. P. | Zendy

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Synthesis of Molecular Vanadium(III) Phosphonates

Author(s) -

Khanra Sumit,

Kloth Marc,

Mansaray Hassanatu,

Muryn Christopher A.,

Tuna Floriana,

Sañudo E. Carolina,

Helliwell Madeleine,

McInnes Eric J. L.,

Winpenny Richard E. P.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701115

Subject(s) - vanadium , cluster (spacecraft) , chemistry , inorganic chemistry , stereochemistry , crystallography , programming language , computer science

All in the family : Organophosphonate complexes of high‐valent vanadium are common, but their V III analogues are few and far between. Reaction of VCl 3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium(III)‐based phosphonates, including the layered {V III 12 (V IV O)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported.

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