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Synthesis of Molecular Vanadium(III) Phosphonates
Author(s) -
Khanra Sumit,
Kloth Marc,
Mansaray Hassanatu,
Muryn Christopher A.,
Tuna Floriana,
Sañudo E. Carolina,
Helliwell Madeleine,
McInnes Eric J. L.,
Winpenny Richard E. P.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200701115
Subject(s) - vanadium , cluster (spacecraft) , chemistry , inorganic chemistry , stereochemistry , crystallography , programming language , computer science
All in the family : Organophosphonate complexes of high‐valent vanadium are common, but their V III analogues are few and far between. Reaction of VCl 3 precursors and phosphonates under solvothermal conditions leads to a family of corresponding vanadium(III)‐based phosphonates, including the layered {V III 12 (V IV O)} cluster shown in the picture (V green, P purple, O red, C black). Preliminary magnetic studies are also reported.