Cation‐Dependent Nonlinear Optical Behavior in an Octupolar 3D Anionic Metal–Organic Open Framework | Zendy

Liu Yan | Zendy; Li Gao | Zendy; Li Xing | Zendy; Cui Yong | Zendy

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Cation‐Dependent Nonlinear Optical Behavior in an Octupolar 3D Anionic Metal–Organic Open Framework

Author(s) -

Liu Yan,

Li Gao,

Li Xing,

Cui Yong

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701056

Subject(s) - nonlinear optical , second harmonic generation , chemistry , ion exchange , metal , chemical physics , metal organic framework , nonlinear optics , ion , crystallography , inorganic chemistry , nonlinear system , optics , organic chemistry , physics , adsorption , laser , quantum mechanics

A holey host : An octupolar porous metal–organic framework with a T d ‐symmetric supercage structure (see picture; green: center of the octapolar structure) exhibits a powder second harmonic generation (SHG) intensity about 15 times higher than that of KH 2 PO 4 . This anionic open framework is highly thermally stable, displays high ion‐exchange capacities with the cations NH 4 + , Na + , and K + , and, more importantly, exhibits an unprecedented cation‐dependent NLO activity.

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