Experimental and Theoretical Studies of the Scandium Carbide Endohedral Metallofullerene Sc 2 C 2 @C 82  and Its Carbene Derivative | Zendy

Iiduka Yuko | Zendy; Wakahara Takatsugu | Zendy; Nakajima Koji | Zendy; Nakahodo Tsukasa | Zendy; Tsuchiya Takahiro | Zendy; Maeda Yutaka | Zendy; Akasaka Takeshi | Zendy; Yoza Kenji | Zendy; Liu Michael T. H. | Zendy; Mizorogi Naomi | Zendy; Nagase Shigeru | Zendy

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Experimental and Theoretical Studies of the Scandium Carbide Endohedral Metallofullerene Sc 2 C 2 @C 82 and Its Carbene Derivative

Author(s) -

Iiduka Yuko,

Wakahara Takatsugu,

Nakajima Koji,

Nakahodo Tsukasa,

Tsuchiya Takahiro,

Maeda Yutaka,

Akasaka Takeshi,

Yoza Kenji,

Liu Michael T. H.,

Mizorogi Naomi,

Nagase Shigeru

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200701049

Subject(s) - carbene , metallofullerene , scandium , derivative (finance) , chemistry , crystallography , density functional theory , fullerene , computational chemistry , organic chemistry , catalysis , financial economics , economics

It's what's on the inside that counts : The structure of Sc 2 C 2 @C 82 (III), as suggested by 13 C NMR spectroscopy and density functional calculations (see picture, left; C red and gray, Sc blue), contains two Sc and two C atoms inside the C 82 cage. This mode of encapsulation is verified by X‐ray single‐crystal analysis of the cycloadduct of Sc 2 C 2 @C 82 (III) and adamantylidene carbene (see picture, right).

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