Propylene Carbonate as a Solvent for Asymmetric Hydrogenations | Zendy

Bayardon Jerome | Zendy; Holz Jens | Zendy; Schäffner Benjamin | Zendy; Andrushko Vasyl | Zendy; Verevkin Sergej | Zendy; Preetz Angelika | Zendy; Börner Armin | Zendy

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Propylene Carbonate as a Solvent for Asymmetric Hydrogenations

Author(s) -

Bayardon Jerome,

Holz Jens,

Schäffner Benjamin,

Andrushko Vasyl,

Verevkin Sergej,

Preetz Angelika,

Börner Armin

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700990

Subject(s) - propylene carbonate , solvent , iridium , catalysis , carbonate , chemistry , organic chemistry , phase (matter) , hydrocarbon , derivative (finance) , hexane , electrode , financial economics , economics , electrochemistry

A penny saved is a penny earned: The use of propylene carbonate as the solvent in iridium‐catalyzed hydrogenations of nonfunctionalized olefins allows efficient catalyst recycling through the formation of two‐phase mixtures with nonpolar solvents such as n ‐hexane. In the picture, the hydrogenated tetrahydronaphthalene derivative is extracted into the hydrocarbon phase.

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