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Formation of Titania/Silica Hybrid Nanowires Containing Linear Mesocage Arrays by Evaporation‐Induced Block‐Copolymer Self‐Assembly and Atomic Layer Deposition
Author(s) -
Chen Xin,
Knez Mato,
Berger Andreas,
Nielsch Kornelius,
Gösele Ulrich,
Steinhart Martin
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700923
Subject(s) - copolymer , atomic layer deposition , materials science , deposition (geology) , evaporation , layer (electronics) , self assembly , nanowire , chemical engineering , layer by layer , nanotechnology , composite material , polymer , physics , geology , paleontology , sediment , engineering , thermodynamics
Hot‐wired silica : Titania‐functionalized silica nanowires containing linear arrays of mesocages (see picture) are prepared by a combination of evaporation‐induced self‐assembly of polystyrene‐ block ‐poly(ethylene oxide) soft templates inside nanoporous hard templates and atomic layer deposition. This combination allows the independent tuning of the internal fine structure of the nanowires and the properties of their outer surface.

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