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Catalytic Activation of Pinacolyl Allylboronate with Indium(I): Development of a General Catalytic Allylboration of Ketones
Author(s) -
Schneider Uwe,
Kobayashi Shū
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700899
Subject(s) - catalysis , indium , reagent , boron , chemistry , metal , group (periodic table) , oxidation state , medicinal chemistry , organic chemistry
Have to B In it to win it! The unprecedented catalytic activation of a Group 13 metal reagent (boron) with a Group 13 metal catalyst in its low oxidation state (indium) was employed for the development of a general catalytic allylboration of ketones. This efficient CC bond‐forming reaction displays high functional group tolerance (see scheme; B(pin)=pinacolyl boronate).