Buckybowls on Metal Surfaces: Symmetry Mismatch and Enantiomorphism of Corannulene on Cu(110) | Zendy

Parschau Manfred | Zendy; Fasel Roman | Zendy; Ernst KarlHeinz | Zendy; Gröning Oliver | Zendy; Brandenberger Louis | Zendy; Schillinger Richard | Zendy; Greber Thomas | Zendy; Seitsonen Ari P. | Zendy; Wu YaoTing | Zendy; Siegel Jay S. | Zendy

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Buckybowls on Metal Surfaces: Symmetry Mismatch and Enantiomorphism of Corannulene on Cu(110)

Author(s) -

Parschau Manfred,

Fasel Roman,

Ernst KarlHeinz,

Gröning Oliver,

Brandenberger Louis,

Schillinger Richard,

Greber Thomas,

Seitsonen Ari P.,

Wu YaoTing,

Siegel Jay S.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700610

Subject(s) - corannulene , monolayer , symmetry (geometry) , crystallography , molecule , metal , chemical physics , symmetry breaking , chemistry , surface (topology) , materials science , computational chemistry , nanotechnology , geometry , physics , organic chemistry , quantum mechanics , mathematics

Fivefold versus twofold: Symmetry‐breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.

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