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Mild Cobalt‐Catalyzed Hydrocyanation of Olefins with Tosyl Cyanide
Author(s) -
Gaspar Boris,
Carreira Erick M.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700575
Subject(s) - hydrocyanation , cyanide , nitrile , cobalt , tosyl , chemistry , catalysis , salient , process (computing) , organic chemistry , computer science , programming language , artificial intelligence
Mild‐mannered and well‐behaved : A conceptually new hydrocyanation reaction for non‐activated olefins provides secondary and tertiary nitriles in good yields under mild conditions. Salient features of this process include broad functional‐group tolerance, readily available starting materials, and ease of execution.