CO 2  Activation by ZnO through the Formation of an Unusual Tridentate Surface Carbonate | Zendy

Wang Yuemin | Zendy; Kováčik Roman | Zendy; Meyer Bernd | Zendy; Kotsis Konstantinos | Zendy; Stodt Dorothee | Zendy; Staemmler Volker | Zendy; Qiu Hengshan | Zendy; Traeger Franziska | Zendy; Langenberg Deler | Zendy; Muhler Martin | Zendy; Wöll Christof | Zendy

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CO 2 Activation by ZnO through the Formation of an Unusual Tridentate Surface Carbonate

Author(s) -

Wang Yuemin,

Kováčik Roman,

Meyer Bernd,

Kotsis Konstantinos,

Stodt Dorothee,

Staemmler Volker,

Qiu Hengshan,

Traeger Franziska,

Langenberg Deler,

Muhler Martin,

Wöll Christof

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700564

Subject(s) - carbonate , electron energy loss spectroscopy , high resolution electron energy loss spectroscopy , spectroscopy , high resolution , chemistry , materials science , crystallography , inorganic chemistry , nanotechnology , metallurgy , geology , physics , remote sensing , quantum mechanics , transmission electron microscopy

Greenhouse gas “al dente” : Exposure of the nonpolar ZnO(10 $\bar 1$ 0) surface to CO 2 at 95 K leads to the formation of an unusual tridentate carbonate species (see picture; C green, O red, Zn gray). Use of several experimental techniques (for example, high‐resolution electron energy loss spectroscopy (HREELS)) and theoretical calculations provides insight into the activation of CO 2 on the surface.

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