Premium Bismuth and Lead Hanging‐Carboxylate Porphyrins: An Unexpected Homobimetallic Lead(II) Complex
Halime Zakaria,
Lachkar Mohammed,
Roisnel Thierry,
Furet Eric,
Halet JeanFrançois,
Boitrel Bernard
Publication year2007
Publication title
angewandte chemie international edition
Resource typeJournals
Strapped in : Insertion of Pb II into a porphyrin bearing 5,15 straps with a pendant carboxylate group led to the first homobimetallic porphyrin complex of a divalent metal ion, which belongs to class III/type M in Buchler's classification of metalloporphyrins (see picture). Since the ligand also readily coordinates the isoelectronic Bi III ion, it is of potential interest as a chelator for 212 Pb/ 212 Bi isotope generators.
Subject(s)bismuth , lead , macrocyclic ligands , o ligands , porphyrinoids
SCImago Journal Rank5.831

Seeing content that should not be on Zendy? Contact us.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here