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Mesoporous Metal–Organic Framework with Rare etb Topology for Hydrogen Storage and Dye Assembly
Author(s) -
Fang QianRong,
Zhu GuangShan,
Jin Zhao,
Ji YanYan,
Ye JunWei,
Xue Ming,
Yang Hua,
Wang Yue,
Qiu ShiLun
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700537
Subject(s) - mesoporous material , hexagonal crystal system , topology (electrical circuits) , metal organic framework , hydrogen storage , luminescence , fluorescence , molecule , materials science , nanotechnology , hydrogen , chemistry , combinatorial chemistry , computer science , inorganic chemistry , crystallography , physics , organic chemistry , optoelectronics , catalysis , combinatorics , mathematics , adsorption , quantum mechanics
More holes than Swiss cheese : A new MOF with the largest reported 1D hexagonal nanotube‐like channels of 24.5 Å×27.9 Å and rare etb topology has been synthesized (see picture). It exhibits good fluorescence properties and substantial hydrogen uptake. For the first time, the compound was assembled with Rh6G dye molecules, and the product showed favorable temperature‐dependent luminescent properties.