Trifluoro‐1,3,5‐tridehydrobenzene | Zendy

Venkataramani Sugumar | Zendy; Winkler Michael | Zendy; Sander Wolfram | Zendy

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Trifluoro‐1,3,5‐tridehydrobenzene

Author(s) -

Venkataramani Sugumar,

Winkler Michael,

Sander Wolfram

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700536

Subject(s) - flash vacuum pyrolysis , flash (photography) , derivative (finance) , trapping , pyrolysis , spectroscopy , argon , quantum chemical , content (measure theory) , chemistry , computer science , physics , organic chemistry , optics , mathematics , quantum mechanics , molecule , geography , financial economics , economics , mathematical analysis , forestry

Three stay, three go : Flash vacuum pyrolysis (FVP) of 1 and subsequent trapping of the products in solid argon at 3 K produces trifluoro‐1,3,5‐tridehydrobenzene ( 2 ). IR spectroscopy, the photochemical behavior, and quantum chemical calculations confirm that for the first time a derivative of the elusive 1,3,5‐tridehydrobenzene could be isolated and spectroscopically characterized.

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