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Trifluoro‐1,3,5‐tridehydrobenzene
Author(s) -
Venkataramani Sugumar,
Winkler Michael,
Sander Wolfram
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700536
Subject(s) - flash vacuum pyrolysis , flash (photography) , derivative (finance) , trapping , pyrolysis , spectroscopy , argon , quantum chemical , content (measure theory) , chemistry , computer science , physics , organic chemistry , optics , mathematics , quantum mechanics , molecule , geography , financial economics , economics , mathematical analysis , forestry
Three stay, three go : Flash vacuum pyrolysis (FVP) of 1 and subsequent trapping of the products in solid argon at 3 K produces trifluoro‐1,3,5‐tridehydrobenzene ( 2 ). IR spectroscopy, the photochemical behavior, and quantum chemical calculations confirm that for the first time a derivative of the elusive 1,3,5‐tridehydrobenzene could be isolated and spectroscopically characterized.