Triazolediylidenes: A Versatile Class of Ligands for the Preparation of Discrete Molecules of Homo‐ and Hetero‐Binuclear Complexes for Improved Catalytic Applications | Zendy

MasMarzá Elena | Zendy; Mata José A. | Zendy; Peris Eduardo | Zendy

Premium

Triazolediylidenes: A Versatile Class of Ligands for the Preparation of Discrete Molecules of Homo‐ and Hetero‐Binuclear Complexes for Improved Catalytic Applications

Author(s) -

MasMarzá Elena,

Mata José A.,

Peris Eduardo

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700535

Subject(s) - iridium , rhodium , janus , catalysis , ligand (biochemistry) , chemistry , molecule , combinatorial chemistry , stereochemistry , materials science , nanotechnology , organic chemistry , receptor , biochemistry

Double trouble : A series of complexes of rhodium and iridium has been obtained with a triazolediylidene ligand, which behaves as an extraordinarily versatile Janus‐type ligand to form dinuclear complexes. The dinuclear complexes showed improved catalytic properties over their mononuclear counterparts. The picture shows a diiridium complex of 1,2,4‐trimethyltriazole‐3,5‐diylidene (Ir gray, C white, N blue, O red, Cl green).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research