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Triazolediylidenes: A Versatile Class of Ligands for the Preparation of Discrete Molecules of Homo‐ and Hetero‐Binuclear Complexes for Improved Catalytic Applications
Author(s) -
MasMarzá Elena,
Mata José A.,
Peris Eduardo
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700535
Subject(s) - iridium , rhodium , janus , catalysis , ligand (biochemistry) , chemistry , molecule , combinatorial chemistry , stereochemistry , materials science , nanotechnology , organic chemistry , receptor , biochemistry
Double trouble : A series of complexes of rhodium and iridium has been obtained with a triazolediylidene ligand, which behaves as an extraordinarily versatile Janus‐type ligand to form dinuclear complexes. The dinuclear complexes showed improved catalytic properties over their mononuclear counterparts. The picture shows a diiridium complex of 1,2,4‐trimethyltriazole‐3,5‐diylidene (Ir gray, C white, N blue, O red, Cl green).