Solvent‐Dependent Oxidation of a (Pyridylmethyl)amino Ligand by FeCl 3  To Give a Water‐Soluble Blue Fluorophore | Zendy

Ostermeier Marc | Zendy; Limberg Christian | Zendy; Ziemer Burkhard | Zendy; Karunakaran Venugopal | Zendy

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Solvent‐Dependent Oxidation of a (Pyridylmethyl)amino Ligand by FeCl 3 To Give a Water‐Soluble Blue Fluorophore

Author(s) -

Ostermeier Marc,

Limberg Christian,

Ziemer Burkhard,

Karunakaran Venugopal

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700389

Subject(s) - chemistry , acetonitrile , ligand (biochemistry) , denticity , dichloromethane , coordination complex , medicinal chemistry , redox , stereochemistry , photochemistry , solvent , crystal structure , inorganic chemistry , organic chemistry , metal , biochemistry , receptor

When having the blues isn't so bad : While normal coordination chemistry is observed when FeCl 3 and the potential ligand 1 (see scheme) are mixed in dichloromethane, redox chemistry occurs in acetonitrile, which involves CH activation and CN bond formation, and finally leads to a water‐soluble blue fluorophore 2 .

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