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Synthesis and Electronic Structure of a Ferroborirene
Author(s) -
Braunschweig Holger,
Fernández Israel,
Frenking Gernot,
Radacki Krzysztof,
Seeler Fabian
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700382
Subject(s) - delocalized electron , ring (chemistry) , electronic structure , chemistry , scheme (mathematics) , product (mathematics) , metal , stereochemistry , computational chemistry , mathematics , organic chemistry , geometry , mathematical analysis
The photochemically induced transfer of a ferroborylene yielded the first metal‐bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant π delocalization in the three‐membered BC 2 ring.