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Rearrangement of a Pd 4 Skeleton from a 1D Chain to a 2D Sheet on the Face of a Perylene or Fluoranthene Ligand Caused by Exchange of the Binder Molecule
Author(s) -
Murahashi Tetsuro,
Kato Naohiro,
Uemura Tomohito,
Kurosawa Hideo
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700340
Subject(s) - fluoranthene , perylene , ligand (biochemistry) , cyclooctatetraene , chemistry , moiety , molecule , stereochemistry , crystallography , photochemistry , anthracene , organic chemistry , biochemistry , receptor
Changing places : A chain‐to‐sheet rearrangement of the Pd 4 moiety (see picture; spheres: Pd, support: organic ligand) takes place during the exchange of one perylene or fluoranthene ligand of a bis(perylene) or a bis(fluoranthene) tetrapalladium sandwich complex by 1,3,5,7‐cyclooctatetraene. These findings are established by X‐ray crystallography and NMR spectroscopy.