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Improved Designs of Metal–Organic Frameworks for Hydrogen Storage
Author(s) -
Han Sang Soo,
Deng WeiQiao,
Goddard William A.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700303
Subject(s) - metal organic framework , hydrogen storage , carbon fibers , bar (unit) , metal , total organic carbon , hydrogen , materials science , chemical engineering , inorganic chemistry , chemistry , environmental chemistry , nanotechnology , organic chemistry , composite material , geology , engineering , composite number , oceanography , adsorption
Quick on the uptake : The metal–organic framework Mg‐MOF‐C30 (see picture) contains Mg 4 O(CO 2 ) 6 building units (pink) and aromatic organic linkers containing 30 carbon atoms (teal). This material leads to 8.08 wt % H 2 uptake at 77 K and 20 bar, the highest among investigated MOF structures.