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Synthesis and Characterization of ( Z )‐[N 3 NFO] + and ( E )‐[N 3 NFO] +
Author(s) -
Wilson William W.,
Haiges Ralf,
Boatz Jerry A.,
Christe Karl O.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700130
Subject(s) - content (measure theory) , fluoride , characterization (materials science) , ion , salt (chemistry) , spectroscopy , nitrogen , nuclear magnetic resonance spectroscopy , chemistry , crystallography , physics , stereochemistry , nanotechnology , materials science , inorganic chemistry , organic chemistry , mathematics , mathematical analysis , quantum mechanics
A new stable polynitrogen ion : The second known example of a stable nitrogen fluoride oxide ion, [N 3 NFO] + , was prepared as its [SbF 6 ] − salt and characterized by multinuclear NMR and vibrational spectroscopy and electronic‐structure calculations. The cation is planar and exists as two stereoisomers (see picture; N blue, O red, F dark blue).
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