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A Large, Bowl‐Shaped {Mo 51 V 9 } Polyoxometalate
Author(s) -
Wang Sheng,
Lin Xiang,
Wan Ying,
Yang Wenbin,
Zhang Shengmin,
Lu Canzhong,
Zhuang Honghui
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200700076
Subject(s) - polyoxometalate , hydroxylamine , chemistry , crystallography , hydrothermal circulation , stereochemistry , materials science , nanotechnology , chemical engineering , organic chemistry , catalysis , engineering
Bowled over : A bowl‐shaped {Mo 51 V 9 } polyoxometalate anion (see picture) is produced in a hydrothermal synthesis by a redox self‐assembly process. This new compound has different building blocks and linkages to previously reported polyoxometalates (see structure; N green, O red, Mo/V gray, threefold axis indicated by black triangle).