A Large, Bowl‐Shaped {Mo 51 V 9 } Polyoxometalate | Zendy

Wang Sheng | Zendy; Lin Xiang | Zendy; Wan Ying | Zendy; Yang Wenbin | Zendy; Zhang Shengmin | Zendy; Lu Canzhong | Zendy; Zhuang Honghui | Zendy

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A Large, Bowl‐Shaped {Mo 51 V 9 } Polyoxometalate

Author(s) -

Wang Sheng,

Lin Xiang,

Wan Ying,

Yang Wenbin,

Zhang Shengmin,

Lu Canzhong,

Zhuang Honghui

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200700076

Subject(s) - polyoxometalate , hydroxylamine , chemistry , crystallography , hydrothermal circulation , stereochemistry , materials science , nanotechnology , chemical engineering , organic chemistry , catalysis , engineering

Bowled over : A bowl‐shaped {Mo 51 V 9 } polyoxometalate anion (see picture) is produced in a hydrothermal synthesis by a redox self‐assembly process. This new compound has different building blocks and linkages to previously reported polyoxometalates (see structure; N green, O red, Mo/V gray, threefold axis indicated by black triangle).

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