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Cover Picture: Multidimensional Large‐Amplitude Motion: Revealing Concurrent Tunneling Pathways in Molecules with Several Internal Rotors / The Glycine–Water Complex (Angew. Chem. Int. Ed. 21/2006)
Author(s) -
Schnell Melanie,
Grabow JensUwe,
Alonso José L.,
Cocinero Emilio J.,
Lesarri Alberto,
Sanz M. Eugenia,
López Juan C.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200690073
Subject(s) - rotational spectroscopy , impulse (physics) , fourier transform , amplitude , molecule , chemistry , microwave , spectroscopy , physics , optics , quantum mechanics , organic chemistry
Microsolvation of glycine has been studied by combining impulse supersonic‐jet Fourier‐transform microwave spectroscopy with laser ablation and the structure of the monohydrated complex derived from rotational spectra. Combining this method with theoretical considerations enables the internal dynamics of multiple large‐amplitude motions, such as in (CH 3 ) 3 XCl (X=Si, Ge, Sn), to be revealed. For more details, see the Communications by J.‐U. Grabow and J. L. Alonso and co‐workers on pages 3465 and 3471 ff.