Premium
Hexasilylated Total Carbomer of Benzene
Author(s) -
Zou Chunhai,
Duhayon Carine,
Maraval Valérie,
Chauvin Remi
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200605262
Subject(s) - benzene , chemistry , aromatization , derivative (finance) , solubility , benzene derivatives , organic chemistry , chemical synthesis , business , catalysis , biochemistry , in vitro , finance
A close cousin of benzene : The cobalt‐assisted reductive aromatization of a hexaalkynyl [6]pericyclyne afforded a fully expanded carbobenzene derivative (see scheme) as the first carbomer without stabilizing aromatic substituents. The triethylsilyl groups ensured high solubility and allowed full spectroscopic characterization of the aromatic macrocycle.