Synthesis and Structure of a Cationic Platinum Borylene Complex | Zendy

Braunschweig Holger | Zendy; Radacki Krzysztof | Zendy; Uttinger Katharina | Zendy

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Synthesis and Structure of a Cationic Platinum Borylene Complex

Author(s) -

Braunschweig Holger,

Radacki Krzysztof,

Uttinger Katharina

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605191

Subject(s) - cationic polymerization , platinum , chemistry , boron , atom (system on chip) , stereochemistry , crystallography , computational chemistry , polymer chemistry , organic chemistry , catalysis , computer science , embedded system

Making a B line : The boryl complex trans ‐[(Cy 3 P) 2 Pt(Br){B(Mes)Br}] was synthesized and converted into the first two‐coordinate borylene complex of platinum, trans ‐[(Cy 3 P) 2 Pt(Br)(BMes)] + (see picture), in which the boron atom is linearly coordinated. The bonding situation was analyzed by theoretical calculations and structural methods. Mes=2,4,6‐Me 3 C 6 H 2 .

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