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Self‐Assembled Supramolecular Bidentate Ligands for Aqueous Organometallic Catalysis
Author(s) -
Machut Cécile,
Patrigeon Julien,
Tilloy Sébastien,
Bricout Hervé,
Hapiot Frédéric,
Monflier Eric
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200605166
Subject(s) - denticity , supramolecular chemistry , organometallic chemistry , aqueous solution , chemistry , catalysis , group 2 organometallic chemistry , combinatorial chemistry , nanotechnology , materials science , organic chemistry , molecule , crystal structure
Sugar snap P : An N,P heterobidentate supramolecular ligand was synthesized in water by mixing a monoamino‐β‐cyclodextrin with an appropriate phosphane. The resultant assembly was used with a platinum(II) salt in aqueous medium to catalyze the hydrogenation of an allylic alcohol (see picture).