Mixed‐Valence Li/Fe‐Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties | Zendy

Férey Gérard | Zendy; Millange Franck | Zendy; Morcrette Mathieu | Zendy; Serre Christian | Zendy; Doublet MarieLiesse | Zendy; Grenèche JeanMarc | Zendy; Tarascon JeanMarie | Zendy

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Mixed‐Valence Li/Fe‐Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties

Author(s) -

Férey Gérard,

Millange Franck,

Morcrette Mathieu,

Serre Christian,

Doublet MarieLiesse,

Grenèche JeanMarc,

Tarascon JeanMarie

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605163

Subject(s) - redox , sorption , valence (chemistry) , metal , lithium (medication) , electrode , metal organic framework , inorganic chemistry , chemistry , materials science , adsorption , organic chemistry , medicine , endocrinology

There's more to LiFe : When used as an electrode in a lithium half cell, the metal–organic framework [Li x Fe II x Fe III 1− x (OH) 0.8 F 0.2 L] (L=O 2 CC 6 H 4 CO 2 ) shows a reversible redox process around 3.0 V versus Li + /Li 0 with interesting capacity retention and rate capability (see voltage profile for a [Li x Fe(OH) 0.8 F 0.2 L] half cell; inset: representation of lithium insertion upon oxidation to Li + ).

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