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Preparation of Molecular Alumoxane Hydrides, Hydroxides, and Hydrogensulfides
Author(s) -
GonzálezGallardo Sandra,
Jancik Vojtech,
CeaOlivares Raymundo,
Toscano Rubén A.,
MoyaCabrera Mónica
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200605081
Subject(s) - chemistry , sulfide , medicinal chemistry , inorganic chemistry , stereochemistry , combinatorial chemistry , organic chemistry
Suppressed aggregation : The unprecedented alumoxane hydrogensulfide [{LAl(SH)} 2 (μ‐O)] and the unique sulfide‐bridged compound [{LAl(SH)} 2 (μ‐S)] can be prepared from the easily accessible aluminum dihydride [LAlH 2 ] (L=HC[(CMe)N(2,4,6‐Me 3 C 6 H 2 )] 2 − ). Owing to the cis conformation of the terminal SH groups, these compounds represent ideal precursors for the synthesis of heterometallic compounds.