Photoisomerizable Heterodienes Derived from a Phosphine Borane | Zendy

Bebbington Magnus W. P. | Zendy; Bontemps Sébastien | Zendy; Bouhadir Ghenwa | Zendy; Bourissou Didier | Zendy

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Photoisomerizable Heterodienes Derived from a Phosphine Borane

Author(s) -

Bebbington Magnus W. P.,

Bontemps Sébastien,

Bouhadir Ghenwa,

Bourissou Didier

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605078

Subject(s) - borane , phosphine , adduct , chemistry , derivative (finance) , photoisomerization , medicinal chemistry , photochemistry , stereochemistry , catalysis , organic chemistry , isomerization , financial economics , economics

Stable relations : Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R= i Pr, R′=mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N α →B to an N β →B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2 .

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