A 1,8‐Naphthylene‐Bridged Bis(indenyl)zinc THF Adduct: Formation and Structure of an ansa‐Zincocene Derivative | Zendy

Wang Huadong | Zendy; Kehr Gerald | Zendy; Fröhlich Roland | Zendy; Erker Gerhard | Zendy

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A 1,8‐Naphthylene‐Bridged Bis(indenyl)zinc THF Adduct: Formation and Structure of an ansa‐Zincocene Derivative

Author(s) -

Wang Huadong,

Kehr Gerald,

Fröhlich Roland,

Erker Gerhard

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605069

Subject(s) - deprotonation , adduct , zinc , chemistry , naphthalene , crystal structure , derivative (finance) , ligand (biochemistry) , stereochemistry , crystallography , medicinal chemistry , organic chemistry , ion , biochemistry , receptor , financial economics , economics

Zinc has the ansa : Deprotonation of the ligand 1,8‐bis(indenyl)naphthalene followed by treatment with ZnCl 2 gives an ansa‐zincocene. Its crystal structure reveals a σ/(σ,π) coordination of the indenyl units to the central zinc atom (see structure; C white, O red, Zn blue).

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