A Cubic 3d–4f Structure with Only Ferromagnetic Gd–Mn Interactions | Zendy

Prasad Thazhe K. | Zendy; Rajasekharan Melath V. | Zendy; Costes JeanPierre | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Cubic 3d–4f Structure with Only Ferromagnetic Gd–Mn Interactions

Author(s) -

Prasad Thazhe K.,

Rajasekharan Melath V.,

Costes JeanPierre

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605062

Subject(s) - prussian blue , polyhedron , ferromagnetism , crystallography , ion , materials science , chemistry , condensed matter physics , physics , mathematics , combinatorics , electrochemistry , organic chemistry , electrode

All aligned : A cubic 3d 5 –4f 7 network of Mn 2+ and Gd 3+ ions is assembled by oxydiacetate (O(CH 2 CO 2 − ) 2 ). The network, which is reminiscent of Prussian blue analogues (see picture; Gd coordination polyhedra: purple, Mn coordination polyhedra: blue, [Mn(H 2 O) 6 ] 2+ : green, H 2 O: red), has a weak but definite ferromagnetic interaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research