Matrix Effect on Motional Coupling and Long‐Range Transport of Cations in Zeolites | Zendy

Jordan Edgar | Zendy; Wilmer Dirk | Zendy; Koller Hubert | Zendy

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Matrix Effect on Motional Coupling and Long‐Range Transport of Cations in Zeolites

Author(s) -

Jordan Edgar,

Wilmer Dirk,

Koller Hubert

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200605049

Subject(s) - sodalite , chemistry , chemical physics , zeolite , conductor , matrix (chemical analysis) , coupling (piping) , range (aeronautics) , thermal conduction , condensation , inorganic chemistry , crystallography , materials science , thermodynamics , organic chemistry , physics , composite material , chromatography , catalysis

Different cation conduction mechanisms in the zeolites cancrinite and sodalite were revealed by the combination of impedance and solid‐state NMR spectroscopies. Cancrinite is a one‐dimensional conductor as a result of its channels, which are made up of stacked 12‐rings, whereas the cation transport in sodalite takes place in three dimensions.

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