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Matrix Effect on Motional Coupling and Long‐Range Transport of Cations in Zeolites
Author(s) -
Jordan Edgar,
Wilmer Dirk,
Koller Hubert
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200605049
Subject(s) - sodalite , chemistry , chemical physics , zeolite , conductor , matrix (chemical analysis) , coupling (piping) , range (aeronautics) , thermal conduction , condensation , inorganic chemistry , crystallography , materials science , thermodynamics , organic chemistry , physics , composite material , chromatography , catalysis
Different cation conduction mechanisms in the zeolites cancrinite and sodalite were revealed by the combination of impedance and solid‐state NMR spectroscopies. Cancrinite is a one‐dimensional conductor as a result of its channels, which are made up of stacked 12‐rings, whereas the cation transport in sodalite takes place in three dimensions.